一、课题组名称：离子吸附科学与技术课题组
二、课题组简介
离子吸附科学与技术课题组面向国家盐湖战略资源高效开发的重大需求，深入开展界面离子输运机制和吸附分离材料体系构建的研究，通过材料吸附位点及路径精准调控和多尺度强化，提高离子分离效率，实现盐湖关键战略资源绿色高效分离。
课题组现有人员25人，固定人员10人（包括研究员1人，副研究员3人），团队专注于吸附剂设计制备、吸附机理研究及吸附分离工艺开发，针对盐湖中锂、铷、铯、硼、溴等的分离提取，设计制备特效复合和电活性吸附剂，系统研究吸附剂的功能结构、吸附/脱附性能、循环使用性能等，从表面和界面的静电作用、构型作用、氢键作用、配位作用、络合作用等方面深入研究吸附机理，开发全新吸附分离工艺。课题组主持中国科学院稳定支持基础研究领域青年团队计划，国家自然科学基金5项（含重点项目），青海省重点研发计划3项，以及其它省部级项目30多项，成员相关成果在PNAS, Angewandte Chemie, Nano letters, AFM, Small, JMCA, CEJ, SPT, JMS, CCS Chemistry等国际期刊发表论文200多篇。
三、课题组组长
刘忠，男，1981年4月生，博士，研究员，博士生导师。2007年7月毕业于中国地质大学（武汉），材料科学与工程学士、岩石矿物材料学硕士；2012年7月毕业于中国科学院山西煤炭化学研究所，材料学博士学位；2014-2015、2018年2次赴英国圣安德鲁斯大学访问学习。担任《Exploration》《International Journal of Minerals, Metallurgy and Materials》期刊青年编委，中国科学院稳定支持基础研究领域青年团队计划负责人，青海省相关人才，青海省自然科学与工程技术学科带头人，入选中国科学院相关人才项目。主持国家自然科学基金重点项目，青海省重点研发计划等项目20余项，获山西省自然科学一等奖，青海省自然科学三等奖。研究领域：（1）吸附表面与界面化学：围绕盐湖资源吸附分离，开展液固界面化学中吸附材料的晶体离子输运、表面结构优化、界面结构调控、分离器件组装等相关研究。（2）吸附分离科学与技术：结合传统吸附工艺，探索电场辅助离子脱吸附，实现盐湖离子吸附提取全流程集成研发。
电话（Tel）：15297182595
邮编（P.C.）：810008
邮箱（Mail）：liuzhong@isl.ac.cn
地址（Add）：青海省西宁市新宁路18号
四、课题组成员
职工：钱志强、卫文飞、雷达、乔英钧、聂国亮、史鹏忠、厍景国、赵炳、张效贤
研究生：詹鸿龙、田晨曦、谭政、胡康、何韵琪
五、课题组人才专员：乔英钧
电话(Tel): 18810673383
邮编(PC):810008
邮箱(Mail): qiaoyj@isl.ac.cn
地址(Add):青海省西宁市新宁路18号
六、招聘/招生信息
面向全国公开招考硕士研究生、博士研究生。博士招生专业包括无机化学、物理化学及材料与化工，硕士招生专业包括无机化学、物理化学、化学工艺及材料与化工。
招收无机化学，材料化学，物理化学，化学工艺，材料与化工等相关专业方向的职工，同时依托所化学学科博士后流动站面向全国招收博士后研究人员。
七、代表性科研项目
盐湖关键战略资源的绿色高效分离，中国科学院稳定支持基础研究领域青年团队计划， 2022.07-2027.07，2000万
盐湖卤水吸附法提锂吸附性能优化及锂硼高效分离研究，国家自然科学基金--区域联合基金（重点项目），2021.01-2024.12，260万
盐湖锂吸附剂的制备及分级电场辅助脱附工艺开发，青海省重点研发与成果转化专项， 2018.01-2021.12，1200万
基于电控离子交换的盐湖提锂工艺技术开发，青海省重点研发与成果转化专项，2024.01-2025.12，600万
稳定铷铯离子磁性吸附剂的构建及表面力学研究，国家自然科学基金--柴达木盐湖化工科学研究联合基金（培育项目），2017.01-2019.12，55万
多梯度限域捕集-强化浓缩电控吸附分离膜的构建及锂富集浓缩，国家自然科学基金--区域创新发展联合基金（重点项目课题），2024.01-2027.12，60万
荧光探针酯基识别位点亲和作用力调控对痕量肼响应速率影响机制研究，国家自然科学基金青年基金，2024.01-2026.12，30万
基于原位拉曼解析聚苯胺电池去离子技术的氯离子去除机理研究，国家自然科学基金-青年基金， 2023.01-2025.12，30万
磁性铁氧化物晶面调控对铯离子吸附剂嫁接性能的影响研究，国家自然科学基金青年项目，2014.01-2016.12，24万
锰系锂离子筛结构调控及抗溶损性研究，青海省国际合作专项，2019.01-2021.12，80万
用于盐湖提铀的氧化石墨烯基复合气凝胶的构筑及构效关系研究，青海省自然科学基金面上项目，2023.03-2025.12，30万
H1.6Mn1.6O4基电控选择性渗透膜的构建及传质反应机制研究，青海省应用基础研究项目，2023.01-2024.12，30万
镁合金表面有机-无机杂化超疏水涂层的构建及其在高盐分环境中的耐腐蚀性能和机制研究，青海省自然基金青年基金项目，2019.01-2021.12，20万
铁氧化合物晶面特性对铯离子磁性吸附剂的影响研究，青海省自然科学基金青年项目，2014.07-2017.07，10万
盐湖原卤电化学离子泵法提锂的竞争吸附机制及电极改性研究，青海省自然科学基金青年项目，2023.01-2025.12，15万
低温至常温条件下含锂盐湖卤水体系相平衡及理论模拟研究，青海省自然科学基金-青年基金项目，2022.01.-2024.12，15万
盐湖卤水提溴用改性聚苯胺电池去离子技术机理研究，青海省自然科学基金-青年基金项目， 2024.01-2016.12，10万
磁性材料及磁性吸附剂的制备，中国科学院青年创新促进会人才项目，2016.01-2019.12，70万
电池去离子技术用电位可控多羰基材料离子选择性提取机理研究目，中国科学院青年创新促进会人才项目，2023.01-2026.12，80万
金属有机框架传感材料设计及其对痕量易制爆危化品的超高灵敏检测机制研究，中国科学院特别研究助理资助项目，2021.01-2024.01，90万
新型铯离子磁性吸附剂的设计与制备，中国科学院西部之光人才项目，中国科学院西部之光人才项目，2016.01-2018.12，52万
镁合金表面仿生超疏水防腐涂层的构建，中国科学院西部之光人才项目，2019.01-2021.12，15万
西藏盐湖电控离子筛提锂研究，万华化学集团股份有限公司，2022.06-2025.05，120万
选择性提取离子用电势区分多官能团材料研发及机制研究，澳门永利娱场官方网骨干人才项目，2022.10-2024.10，20万
基于多尺度理论模拟的轻金属离子扩散吸附分离机制研究，澳门永利娱场官方网骨干人才项目，2024.04-2027.04，40万
八、代表性科研成果
论文：
Qiao Y., Dai X., Zhao B., Qian Z., Wu Z., Liu Z., Enhanced lithium extraction from aqueous solutions using multi-scale modified titanium adsorbent. Separation and Purification Technology, 2024, 351, 128060.
Xiao F., Lei D., Liu C., Li Y., Ren W., Li J., Li D., Zu B., Dou X., Coherent modulation of the aggregation behavior and intramolecular charge transfer in small molecule probes for sensitive and long-term nerve agent monitoring. Angewandte Chemie International Edition, 2024, 63, e202400453.
Yan T., Hou H., Wu C., Cai Y., Yin A., Cao Z., Liu Z., He P., Xu J., Unraveling the molecular mechanism for enhanced gas adsorption in mixed-metal MOFs via solid-state NMR spectroscopy, Proc. Natl. Acad. Sci. 2024, 121(6), e2312959121.
Shi P., Wang K., Chen Z., Wang J., Lin K., Solange N., Yue Y., Guo Z., Symmetric variation of monomers for constructing 1D/2D imine-based covalent organic frameworks. CCS Chemistry, 2024, 6, 941-952.
She J., Chen X., Gao H., Song Z., Shi L., Li J., Lu X., Wu C., ‘Green’ fabrication of PVC ultrafiltration membranes with high-flux and improved hydrophilicity by in-situ interpenetration of hydrophilic crosslinking networks. Journal of Membrane Science, 2024, 693, 122383.
Wu Y., Lei D., Li J., Luo Y., Du Y., Zhang S., Zu B., Su Y., Dou X., Controlled synthesis of preferential facet-exposed Fe-MOFs for ultrasensitive detection of peroxides. Small, 2024, 20, 2401024.
Luo Y., Lei D., Li M., Ge Y., Li J., Zu B., Yao J., Dou X., Fluorophore branching boosted photo-induced energy transfer in UiO-66 for ultrasensitive and instant hydrazine sensing. Journal of Materials Chemistry A, 2024, 12, 12088-12097.
Feng Y., Lei D., Zu B., Li J., Li Y., Dou X., A self-accelerating naphthylamide-based probe coupled with up-conversion nanoparticles for ultra-accurate tri-mode visualization of hydrogen peroxide. Advanced Science, 2024, 11, 2309182.
She J., Gao H., Song Z., Shi L., Li J., Lu X., Wu C., Improvement of persistent hydrophilicity and pore uniformity of polyvinyl chloride ultrafiltration membranes by in-situ crosslinking reaction assisted phase separation. Journal of Membrane Science, 2023, 684, 121884.
She J., Gao H., Song Z., Shi L., Liu S., Li J., Lu X., Wu C., N-methylglucamine modified poly (vinyl chloride) support assists the construction of uniform dually charged nanofiltration membrane via interfacial polymerization. Separation and Purification Technology, 2023, 307, 122674.
Shi P., Wang J., Guo Z., A one-dimensional covalent organic framework film for near-infrared electrochromism. Chemical Engineering Journal, 2023, 451139082.
Zhao B., Qiao Y., Qian Z., Wei W., Li J., Wu Z., Liu Z., Unraveling the Li+ desorption behavior and mechanism of Li4Ti5O12 with different facets to enhance lithium extraction. Journal of Materials Chemistry A, 2023, 11, 7094-7104.
Sun C., Zhao B., Mao J., Dai K., Wang Z., Tang L., Chen H., Zhang X., Zheng J., Enhanced cycling stability of 4.6 V LiCoO2 cathodes by inhibiting catalytic activity of its interface via mxene modification. Advance Functional Materials, 2023, 33, 2300589.
Chen Y., Zhan H., Qiao Y., Qian Z., Lv B., Wu Z., Liu Z., Facet dependent ion channel of iron phosphate for electrochemical lithium extraction. Chemical Engineering Journal, 2023, 477, 147136.
Zhan H., Qiao Y., Qian Z., Li J., Wu Z., Liu Z., Electrochemical behaviors of porous spherical spinel H1.6Mn1.6O4 with high Li+ adsorption capacity. Separation and Purification Technology. 2023, 305, 122485.
Zhao B., Qian Z., Qiao Y., Li J., Wu Z., Liu Z., The Li(H2O)n dehydration behavior influences the Li+ ion adsorption on H4Ti5O12 with different facets exposed. Chemical Engineering Journal, 2023, 451, 138870-138882.
Shi P., Qin Ji., Luo S., Hao P., Li N., Zan X., Effect of the stiffness of one-layer protein-based microcapsules on dendritic cell uptake and endocytic mechanism, Biomaterials Science. 2022, 10, 178-188.
Nie G., Cui R., Li W., Stable Phase equilibria of the quaternary system LiBr-NaBr-KBr-H2O and the ternary system LiBr-KBr-H2O at 323.15 K. Journal of Chemical & Engineering Data, 2022, 68, 229-235.
Nie G., Cui R., Liu Z., Li W., Solid-liquid phase equilibria of quaternary system LiBr-NaBr-KBr-H2O and its subsystems at 348.15 K. ACS Omega, 2022, 7, 46594-46601.
Zhan H., Qiao Y., Qian Z., Li J., Wu Z., Hao X., Liu Z., Manganese-based spinel adsorbents for lithium recovery from aqueous solutions by electrochemical technique. Journal of Industrial and Engineering Chemistry, 2022, 114:142-150.
Qian Z., Liu Z., Wang S., Ye X., Wu Z., Preparation and anti-corrosion properties of SiO2@MWCNTs@PFOTES superhydrophobic coatings on magnesium alloy. International Journal of Electrochemical Science. 2022, 17, 220129.
Liu H., Tian D., Ouyang M., Qian Z., Wang X., Morphology-controlled fabrication of magnetic phase-change microcapsules for synchronous efficient recovery of wastewater and waste heat. J. Colloid Interface Sci., 2022, 608, 1497.
Wei W., Gu X., Wang R., Feng X., Chen H.*, Wood-based Self-supporting Nanoporous Three-dimensional Electrode for High-efficient Battery Deionization. Nano letters, 2022, 22, 7572-7578.
Wei W., Feng X., Wang R., Zheng R., Yang, D., Chen, H.*. Electrochemical Driven Phase Segregation Enabled Dual-ion Removal Battery Deionization Electrode. Nano letters, 2021, 11, 4830-4837
Shi P., Qin J., Wu X., Wang L., Zhang T., Yang D., Zan X., Appelhans D., Sheltering proteins from protease-mediated degradation and a de novo strategy for preventing acute liver injury. Biomaterials Science, 2021, 9, 4423-4427
Shi P., Zhou D., Zhu Y., Peng B., Shao N., Zan X., Thrombin-loaded TA-CaCO3 microspheres as a budget, adaptable, and highly efficient hemostatic. ACS Applied Bio Materials, 2021, 4, 1030-1037.
Liu H., Zheng Z., Qian Z., Wang Q., Wu D., Wang X., Lamellar-structured phase change composites based on biomass-derived carbonaceous sheets and sodium acetate trihydrate for high-efficient solar photothermal energy harvest, Solar Energy Materials and Solar Cells, 2021, 229, 111140
Liu H., Qian Z., Wang Q., Wu D., Wang Xi., Development of renewable biomass-derived carbonaceous aerogel/mannitol phase-change composites for high thermal-energy-release efficiency and shape stabilization, ACS Applied Energy Materials, 2021, 4, 1714-1730.
Qian Z., Liu Z., Wang S., Ye X., Wu Z., A durable PVDF/PFOTES-SiO2 superhydrophobic coating on AZ31B Mg alloy with enhanced abrasion resistance performance and anti-corrosion properties. Applied Sciences-Basel, 2021, 11(23), 11172.
Qian F., Zhao B., Guo M., Wu Z., Zhou W., Liu Z., Surface trace doping of Na enhancing structure stability and adsorption properties of Li1.6Mn1.6O4 for Li+ recovery. Separation and Purification Technology, 2021, 256, 117583-117593.
Zhao B., Qian F., Guo M., Wu Z., Liu Z., The performance and mechanism of recovering lithium on H4Ti5O12 adsorbents influenced by (110) and (111) facets exposed. Chemical Engineering Journal, 2021, 414, 128729.
Qian F., Guo M., Qian Z., Zhao B., Li J., Wu Z., Liu Z., Enabling highly structure stability and adsorption performances of Li1.6Mn1.6O4 by Al-gradient surface doping. Separation and Purification Technology, 2021, 264, 118433-118443.
Nie G., Sang S., Ye C., Gao Y., He C., Solubilities of salts in quaternary system KBr-K2SO4-K2B4O7-H2O and quinary system KCl-KBr-K2SO4-K2B4O7-H2O at 373 K. Russian Journal of Physical Chemistry A, 2021, 95, 1372-1377.
Nie G., Cui R., Sang S., Wu Z., Ye C., Experimental study and theoretical simulation of fluid phase equilibrium in the subsystems of quinary system NaBr-KBr-MgBr2-SrBr2-H2O at 298 K. Journal of Molecular Liquids, 2020, 306, 112635.
Nie G., Sang S., Cui R., Wu Z., Ye C., Gao Y., Measurements and calculations of solid-liquid equilibria in two quaternary systems: LiCl-NaCl-SrCl2-H2O and LiCl-KCl-SrCl2-H2O at 298 K. Fluid Phase Equilibria, 2020, 509, 112458.
Wang S., Ye X., Zhang H., Qian Z., Li Q., Wu Z., Li S., Superhydrophobic silane/fluorinated attapulgite@SiO2 composite coatings on magnesium alloy for corrosion protection. ChemistrySelect, 2020, 5, 10329-10338.
Qian F., Zhao B., Guo M., Qian Z., Wu Z., Liu Z., Trace doping by fluoride and sulfur to enhance adsorption capacity of manganese oxides for lithium recovery. Materials & Design, 2020, 194, 108867-108878.
Qian F., Zhao B., Guo M., Qian Z., Xu N., Wu Z., Liu Z., Enhancing the Li+ adsorption and anti-dissolution properties of Li1.6Mn1.6O4 with Fe, Co doped. Hydrometallurgy, 2020, 193, 105291-105298.
Qian F., Zhao B., Guo M., Li J., Liu Z., Wu Z., K-Gradient Doping to Stabilize Spinel Structure of Li1.6Mn1.6O4 for Li+ Recovery. Dalton Transactions, 2020, 49, 10939-10949.
Zhao B., Guo M., Qian Z., Li J., Wu Z., Liu Z., The adsorption behavior of lithium on spinel titanium oxide nanosheets with exposed (114) high-index facets. Dalton Transactions, 2020, 49, 14180-90.
Zhao B., Guo M., Qian F., Qian Z., Xu N., Wu Z., Liu Z., Hydrothermal synthesis and adsorption behavior of H4Ti5O12 nanorods along [100] as lithium ion-sieves. RSC Advances, 2020, 10, 35153-35163.
Xu N., Li S., Li W., Liu Z., Removal of fluoride by graphene oxide/alumina nanocomposite: adsorbent preparation, characterization, adsorption performance and mechanisms. ChemistrySelect, 2020, 5, 1818-1828.
Cao Y., Wang H., Ding R., Wang L., Liu Z., Lv B., Highly efficient oxidative desulfurization of dibenzothiophene using Ni modified MoO3 catalyst. Applied Catalysis A: General, 2020, 589, 117308.
Shi P., Qin J., Wu X., Wang L., Zhang T., Yang D., Zan X., Appelhans D., A facile and universal method to efficiently fabricate diverse protein capsules for multiple potential applications. ACS Applied Materials & Interfaces, 2019, 11(42): 39209-39218.
Shi P., Qin J., Hu J., Bai Y., Zan X., Insight into the mechanism and factors on encapsulating basic model protein, lysozyme, into heparin doped CaCO3. Colloids and Surfaces B: Biointerfaces, 2019, 175: 184-194.
Nie G., Sang S., Cui R., Measurements of the solid-liquid phase equilibria in quinary system NaBr-KBr-MgBr2-SrBr2-H2O at 323 K. Journal of Chemical and Engineering Data, 2019, 64, 3436-3443.
Nie G., Sang S., Cui R., Solid-liquid equilibrium phase diagram and calculation in the quaternary system (KBr-NaBr-MgBr2-H2O) at 298K. Journal of Solution Chemistry, 2019, 48, 862-874.
Liu Z., Zhou Y., Guo M., Lv B., Wu Z., Zhou W., Experimental and theoretical investigations of Cs+ adsorption on crown ethers modified magnetic adsorbent. Journal of Hazardous Materials, 2019, 371, 712-720.
Qian F., Guo M., Qian Z., Li Q., Wu Z., Liu Z., Highly lithium adsorption capacities of H1.6Mn1.6O4 ion-sieve by ordered array structure. ChemistrySelect, 2019, 4, 10157-10163.
Xu N., Li S., Guo M., Qian Z., Li W., Liu Z., Synthesis of H4Mn5O12 nanotubes lithium ion sieve and its adsorption properties for Li+ from aqueous solution. ChemistrySelect, 2019, 4, 9562-69.
Shi P., Luo S., Voit B., Appelhans D., Zan X., A facile and efficient strategy to encapsulate the model basic protein lysozyme into porous CaCO3. Journal of Materials Chemistry B, 2018, 6, 4205-4215.
Qian Z., Wang S., Ye X., Liu Z., Wu Z., Corrosion resistance and wetting properties of silica-based superhydrophobic coatings on AZ31B Mg alloy surfaces, Applied Surface Science, 2018, 453, 1-10.
Yu X., Zhao C., Zhang T., Liu Z., Molecular and dissociative O2 adsorption on the Cu2O (111) surface. Physical Chemistry Chemical Physics, 2018, 20, 20352-20362.
Yu X., Zhang X., Meng Y., Zhao Y., Li Y., Xu W., Liu Z., CO adsorption, dissociation and coupling formation mechanisms on Fe2C (001) surface. Applied Surface Science, 2018, 434, 464-472.
Liu Z., Yu R., Dong Y., Li W., Lv B., The adsorption behavior and mechanism of Cr(VI) on 3D hierarchical a-Fe2O3 structures exposed by (001) and non-(001) planes. Chemical Engineering Journal. 2017, 309, 815-823.
Xu N., Liu Z., Dong Y., Hong T., Li D., Li W., Controllable synthesis of mesoporous alumina with large surface area for high and fast fluoride removal, Ceramics International, 2016, 42, 15253-15260.
Xu N., Liu Z., Bian S., Dong Y., Li W., Preparation of MnO2-Al2O3 adsorbent with large specific surface area for fluoride removal. Particuology, 2016, 27, 66-71.
Liu Z., Chiang C., Li W., Zhou W., The role of surface hydrolysis of ferricyanide anions in crystal growth of snowflake-shaped α-Fe2O3. Chemical Communications, 2015, 51, 9350-9353.
Wang Y., Liu Z., Li D., Liu Z., Dong Y., Li W., Li N., The polymeric nanofilm of triazinedithiolsilane fabricated by self-assembled technique on copper surface. Part 1: Design strategy and corrosion resistance. Corrosion Science. 2015, 98, 382-390.
Liu Z., Lv B., Xu Y., Li W., Hexagonal α-Fe2O3 nanorods bound by high-index facets as high-performance electrochemical sensor. Journal of Materials Chemistry A, 2013, 1, 3040-3046.
专利：
一种基于流动电容去离子技术的盐湖粗化学品的除杂方法，ZL202310236816.3，2023.07.04
一种盐湖有价资源锂、铷、铯、溴和碘的分离提取方法，ZL202310236769.2，2023.07.07
电化学提锂电极以及电化学提锂方法，ZL202310236709.0，2023.08.08
锂吸附剂、其制备方法及锂离子的提取方法，ZL202210838498.3，2023.06.02
一种锂吸附材料及其制备方法和应用，ZL202210825473.X，2023.06.23
一种带有球磨功能的固液反应搅拌桨及搅拌器，ZL202021933898.5，2021.05.07
一种锂离子吸附材料制备方法，ZL202010479045.7，2023.07.28
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一种多孔锰系锂离子筛吸附剂及其制备方法，ZL201811494510.3，20210716
一种六方片状锰系锂离子筛吸附剂及其制备方法，ZL201811495626.9，2021.04.02
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