一、课题组名称:相分离技术与应用课题组
二、课题组简介
三、课题组组长
付振海,男,1985年生于青海省海南州兴海县。现任澳门永利娱场官方网副研究员,硕士生导师,相分离技术与应用课题组组长。2003至2007年在北京化工大学应用化学系获得学士学位,2011年获得北京化工大学化学工程与技术硕士学位,2011年到澳门永利娱场官方网参加工作,2017年在兰州大学获得无机化学博士学位。入选中科院“青促会”、中科院西部之光“西部青年学者”、青海省培养人才计划项目。目前主要研究领域为盐湖资源分离提取、高端化学品制备科学。主要包括钾盐、镁盐、锂盐等绿色分离加工技术、高端化学品材料及器件等。发表研究论文20余篇,申请专利20余件。
学术兼职:《盐湖研究》编委、青海省海西科技咨询专家库专家。
电话(Tel):18009713628
邮编(P.C.):810008
邮箱(Mail):fzh@isl.ac.cn
地址(Add):青海省西宁市新宁路18号
四、课题组成员
职工:张志宏、李成宝、苏彤、马艳芳、张世春、李志伟、焦爱军
研究生:段友康、黄守燕、俞学山
五、课题组人才专员:苏彤
电话(Tel):18997061039
邮编(P.C.):810008
邮箱(Mail):stxmeng@isl.ac.cn
地址(Add):青海省西宁市新宁路18号
六、招聘信息
招人数量:2-3名
研究方向:分离与提纯、电化学、功能材料
专 业:化学、化工、材料相关专业
七、招生信息
招人数量:1-2名
专 业:化学、化工、材料相关专业
八、科研项目
1.盐湖镁资源功能化利用关键技术研究与工业示范,青海省科技厅重大科技专项,2015.01-2017.12
2.氯化钾“冷结晶-正浮选”工艺提升光卤石原矿适应性技术研究与工程应用,中国科学院STS区域重点项目,2021.1.1-2023.12.31
3.盐湖老卤制备无水氯化镁关键技术研究及应用,青海省科技厅重大科技专项,2021.05-2022.12
4.智能化盐田精控技术研究与示范, 青海省科技厅重点研发与转化计划,2019.01-2021.12.
5.低钠盐制备工艺技术研究与示范,青海省科技厅重点研发与转化计划,2023.01-2025.12
6.细粒高钠光卤石矿高效生产氯化钾技术研究及工程应用,青海省科技厅重点研发与转化计划,2021.01.-2023.12
7.盐析法从沉锂母液中制备碳酸锂技术研究与应用,青海省科技厅重点研发与转化计划,2022.01.-2024.12。
8.荧光化学传感器的设计及性能研究,中国科学院青年创新促进会人才项目,2018.01-2021.12
9.高效选择镁离子荧光探针的设计合成及性能研究,青海省自然科学基金,2019.01-2021.12
10.电池级Li2CO3晶体的连续反应制备技术研究,中国科学院西部青年学者计划,2018.01-2021.12
11.盐湖Li2CO3晶体的生长和形貌影响及调控研究, 中国科学院绿色过程制造创新研究院联合基金, 2020.06-2023.05
12.拉果错碳酸锂盐田工艺技术研究, 横向课题, 2018.07-2022.12
13.拉果错盐湖卤水自然蒸发实验研究, 横向课题, 2010.01-2022.12
14.从拉果错盐湖卤水中分离提取铷铯工艺研究,企业委托,2018.07-2019.12
九、代表性科研成果
1.论文及论著
(1) Xueshan Yu, Zhenhai Fu*, Yanfang Ma, Chengbao Li, Shichun Zhang, Zhihong Zhang*. Polyethylene glycol regulated carnallite decomposition-crystallization: Experimental and theoretical analysis. Minerals Engineering, 2023, 195, 108021.
(2) Jing-Can Qin, Zhi-Wei Li, Zhen-Hai Fu*, Zhi-Hong Zhang. Development of a NIR fluorescent probe for detection of cysteine and its application in bioimaging. Sensors and Actuators B: Chemical 2022, 357, 131430.
(3) Xiang Li, Zhenhai Fu*, Yingjun Qiao, Zhihong Zhang*, Yuan Zhou, Chunxi Hai, Yue Shen, Yanxia Sun, Jinbo Zeng, and Xiufeng Ren. Preparation, Characterization, and Modification of Sodium Acetate Trihydrate-Urea Binary Eutectic Mixtures As Phase Change Material. Energy & Fuels 2020, 34, 5, 6439–6447.
(4) Zhiwei Li, Zhenhai Fu*, Chengbao Li, Dongmei Zhao, Yongming Zhang, Yanfang Ma, Zhihong Zhang. Prediction of brine evaporation rate based on response surface methodology and artificial neural network. Desalination and Water Treatment, 2021 (231):143–151.
(5) Zhen-Hai Fu, Xiao Han, Yongliang Shao, Jianguo Fang, Zhi-Hong Zhang, Ya-Wen Wang*, and Yu Peng*. Fluorescein-Based Chromogenic and Ratiometric Fluorescence Probe for Highly Selective Detection of Cysteine and Its Application in Bioimaging. Analytical Chemistry 2017, 89, 1937?1944.
(6) Zhen-Hai Fu, Ya-Wen Wang*, and Yu Peng*. Two fluorescein-based chemosensors for the fast detection of 2,4,6-trinitrophenol (TNP) in water. Chemical Communications 2017, 53, 10524?10527.
(7) Zhen-Hai Fu*, Jing-Can Qin, Ya-Wen Wang, Yu Peng, Yong-Ming Zhang, Dong-Mei Zhao, Zhi-Hong Zhang. A quinoline-based chromogenic and ratiometric fluorescent probe for selective detection of Mg2+ ion: Design, synthesis and its application in salt lake brines and bioimaging. Dyes and Pigments 2021, 185, 108896.
(8) Zhen-Hai Fu, Lu-Bin Yan, Xiaolong Zhang, Fan-Fan Zhu, Xin-Long Han, Jianguo Fang, Ya-Wen Wang*, and Yu Peng*. A fluorescein-based chemosensor for relay fluorescence recognition of Cu(ii) ions and biothiols in water and its applications to a molecular logic gate and living cell imaging. Organic & Biomolecular Chemistry 2017, 15, 4115?4121.
(9) Jing-Can Qin, Min Wang, Zhen-Hai Fu*, Zhi-Hong Zhang. Design and synthesis of a solvent-dependent fluorescent probe for dual selective detection of Mg2+ ion and Zn2+ ion. Journal of Photochemistry and Photobiology A: Chemistry 2021, 405, 112965
(10) Min Wang, Yong-Ming Zhang, Qin-Yi Zhao, Zhen-Hai Fu*, Zhi-Hong Zhang*. A new acetal as a fluorescent probe for highly selective detection of Fe3+ and its application in bioimaging. Chemical Physics 2019, 527, 110470.
(11) 余建荣,李成宝,汪云川等. 老挝固体钾盐矿选矿设计的优化与创新—以开元500 Kt/a氯化钾项目为例. 盐湖研究,2019, 12: 28-36
(12) Yan-Fang Ma, Shao-Ji Xiang, Zhen-Hua Cui, Kan-She Li*, Zhi-hong Zang. Molecular Dynamic Regulation of Na and Mg Ions on Lithium Carbonate Crystallisation in Salt Lakes. Journal of Wuhan University of Technology-Mater, 2021,36:22-28.
(13) Yanfang Ma, Xin Liu, Wanqiu Dong, Kanshe Li*, Zhihong Zhang*. Molecular dynamic Study on changing pH Trends in Salt Brine Evaporation. Desalination and Water Treatment, 2022, 250: 44-50
(14) Yan-Fang Ma, Kan-She Li*, Zhi-Hong Zhang, Xin Liu, Dong-Mei Zhao. Li+ enrichment behavior in a sodium sulfate and low carbonate salt lake brine. Results in Materials, 2020,7:100-107
(15) Xin Liu, Yanfang Ma*, Guojian Liu, Zhenhua Cui, Shaoji Xiang. Magnesium ion effect in the process of lithium migration in salt lake. Desalination and Water Treatment, 2022, 250: 148-158
(16) 刘鑫,马艳芳*,刘国建,崔振华,张志宏*.基于密度泛函理论研究K对Li2CO3晶体影响规律. 盐湖研究, 2022, 30(1): 68-76
(17) Yan-Fang Ma, Jian-Chuan Liu*, Kan-She Li*, Zhi-hong Zang. Lithium behavior in Salt-water System Explored by Molecular Dynamics Simulation. Journal of Wuhan University of Technology-Mater, 2020, 35:1016-1102
(18) Yan-Fang Ma, Kan-She Li*, Zhi-Hong Zhang, Zhou Bing, Jian-kang Wang, Tian-Qi Hu. Study of simulated Kinetics Mining Underground Carnallite. Science Discovery, 2016; 4: 462-466
(19) Ai-Jun Jiao, Jian-Fei Gao, Zheng-Hua He, Jing-Feng Hou, Ling-Bin Kong*, Manganese fluoride as non-battery type anode for high performance Li-ion capacitors. Journal of Energy Storage, 2022, 47: 103594.
(20) Ai-Jun Jiao, Jian-Fei Gao, Zheng-Hua He, Jing-Feng Hou, Ling-Bin Kong*, Nickel Fluoride Nanorods as Anode Materials for Li-Ion Hybrid Capacitors. ACS Applied Nano Materials, 2021, 4: 11601-11610.
2.专利及软著等
(1).一种用于提升氯化钾品位的方法及应用, 202210554471.1, 发明专利, 2022.5.19。
(2). 用于检测镁离子的比率型荧光探针、其制备方法及应用, CN202010822385.5;发明专利,2023.3.21。
(3). 一种细粒高钠光卤石生产高品位农用氯化钾的方法, CN202111497651.2; 发明专利,2022.1.21。
(4).一种提高硫酸钠亚型盐湖卤水中的Li+收率的方法, ZL.202110139714.0,发明专利,2022.4.15。
(5). 一种盐湖富锂卤水制备大颗粒碳酸锂的方法,ZL2019 1 0607878.6,发明专利,2022.3.11。
(6). 从硫酸钠亚型盐湖卤水中分离镁锂并富集锂的方法,ZL 2018 1 1190389.5,发明专利,2022.12.11。
(7). 一种硫酸钠亚型盐湖卤水脱硫并富集锂的方法,ZL 2019 1 0533975.3,发明专利,2022.11.06。
(8). 一种卤水中铀元素的富集方法,ZL 2016 1 0815998.X,发明专利,2018.10.2。
(9). 一种碳酸盐型盐湖卤水锂的富集方法,ZL 2013 1 0320903.3,发明专利,2018.2.18。
(10). 从杂卤石矿中静态溶浸提取钾以及制备硫酸钾的方法,ZL 2013 1 0320200.0,发明专利,2013.07.26。
(11).中科院青海盐湖研究所.盐湖卤水比蒸发系数计算软件 [简称:BEC]V1.0.2019SR0247546。
(12).中科院青海盐湖研究所.盐湖卤水蒸发量计算软件 [简称:BEF]V1.0.2019SR0242936。
(13).中科院青海盐湖研究所.青海盐湖工业股份有限公司. 智能化盐田工艺计算管理软件 [简称:盐田工艺管理软件]V1.0。2021SR1834306。